Lesson 391 of 1524
Equilibria of Other Reaction Classes
Complex ions are examples of Lewis acid-base adducts and comprise central metal atoms or ions acting as Lewis acids bonded to molecules or ions called ligands that act as Lewis bases.
Practice this chapterComplex ions are examples of Lewis acid-base adducts and comprise central metal atoms or ions acting as Lewis acids bonded to molecules or ions called ligands that act as Lewis bases. A Lewis acid is a species that can accept an electron pair, whereas a Lewis base has an electron pair available for donation to a Lewis acid.
The equilibrium constant for an equilibrium involving the precipitation or dissolution of a slightly soluble ionic solid is called the solubility product, K sp , of the solid. For a heterogeneous equilibrium involving the slightly soluble solid M p X q and its ions M m+ and X n-
complex ion — ion consisting of a central atom surrounding molecules or ions called ligands via coordinate covalent bonds. ligand — molecule or ion acting as a Lewis base in complex ion formation; bonds to the central atom of the complex. Lewis acid-base adduct — compound or ion that contains a coordinate covalent bond between a Lewis acid and a Lewis base. Lewis acid — any species that can accept a pair of electrons and form a coordinate covalent bond.
Worked example
What does “complex ion” mean in Equilibria of Other Reaction Classes?
- 1Use the wording this chapter gives for complex ion.
- 2The book says: ion consisting of a central atom surrounding molecules or ions called ligands via coordinate covalent bonds.
- 3Do not use the meaning of ligand. That term means molecule or ion acting as a Lewis base in complex ion formation; bonds to the central atom of the complex.
Result: ion consisting of a central atom surrounding molecules or ions called ligands via coordinate covalent bonds
Why. That is the meaning this chapter gives for complex ion.
Do not swap complex ion and ligand. complex ion means ion consisting of a central atom surrounding molecules or ions called ligands via coordinate covalent bonds. ligand means molecule or ion acting as a Lewis base in complex ion formation; bonds to the central atom of the complex.
Practice margin
This chapter
A fresh set from this chapter only. Choose 10 or 20. Multiple choice and fill-in, with no repeat inside the set.