Lesson 966 of 1524
Carboxylic Acids and Nitriles
Like aldehydes and ketones, the carbonyl carbon atom is sp 2 -hybridized; like alcohols, carboxylic acids are associated through hydrogen-bonding and therefore have high boiling points
Practice this chapterLike aldehydes and ketones, the carbonyl carbon atom is sp 2 -hybridized; like alcohols, carboxylic acids are associated through hydrogen-bonding and therefore have high boiling points Although weaker than mineral acids such as HCl, carboxylic acids dissociate much more readily than alcohols because the resultant carboxylate ions are stabilized by resonance between two equivalent forms
Carboxylic acids are among the most useful building blocks for synthesizing other molecules, both in nature and in the laboratory. Thus, an understanding of their properties and reactions is fundamental to understanding biological chemistry.
carbonyl carbon atom — sp 2 -hybridized; like alcohols, carboxylic acids are associated through hydrogen-bonding and therefore have high boiling points. resultant carboxylate ions — stabilized by resonance between two equivalent forms.
Worked example
What does “carbonyl carbon atom” mean in Carboxylic Acids and Nitriles?
- 1Use the wording this chapter gives for carbonyl carbon atom.
- 2The book says: sp 2 -hybridized; like alcohols, carboxylic acids are associated through hydrogen-bonding and therefore have high boiling points.
- 3Do not use the meaning of resultant carboxylate ions. That term means stabilized by resonance between two equivalent forms.
Result: sp 2 -hybridized; like alcohols, carboxylic acids are associated through hydrogen-bonding and therefore have high boiling points
Why. That is the meaning this chapter gives for carbonyl carbon atom.
Do not swap carbonyl carbon atom and resultant carboxylate ions. carbonyl carbon atom means sp 2 -hybridized; like alcohols, carboxylic acids are associated through hydrogen-bonding and therefore have high boiling points. resultant carboxylate ions means stabilized by resonance between two equivalent forms.
Practice margin
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